|
|
demethylsuberosin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (+)-marmesin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.66
marmesin synthase
|
–
|
|
MetaCyc:
RXN-8383
|
|
|
|
S-adenosyl-L-methionine + bergaptol <=> H+ + bergapten + S-adenosyl-L-homocysteine
|
2.1.1.69
5-hydroxyfuranocoumarin 5-O-methyltransferase
|
–
|
|
BRENDA:
BR43912
KEGG:
R02882
MetaCyc:
2.1.1.69-RXN;
RXN-8448
|
|
|
|
psoralen + NADPH + O2 + H+ <=> bergaptol + NADP+ + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-8387
|
|
|
|
dimethylallyl_diphosphate + umbelliferone <=> diphosphate + demethylsuberosin
|
2.5.1.139
umbelliferone 6-dimethylallyltransferase
|
–
|
|
BRENDA:
BR51973
KEGG:
R08996
MetaCyc:
RXN-8382
|
|
|
|
(+)-marmesin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> psoralen + oxidized_[NADPH-hemoprotein_reductase] + acetone + H2O
|
1.14.14.141
psoralen synthase
|
–
|
|
MetaCyc:
RXN-8386
|
|